AP Chemistry 2024-2025

Copper will not oxidize when exposed to 1 M strong acids since its reduction potential 0.80 V is greater than the reduction potential of H+.

Copper ions would even oxidize hydrogen gas to reform copper metal.

Cu(s) + 2 H+(aq) ← Cu2+(aq) + 2 H2(g)

However nitric acid can oxidize copper metal.

Nitric acid is a strong acid, but in addition its nitrate ions in an acidic environment have a higher reduction potential than hydrogen ions and can oxidize with metals that regular acids can't.

Nitric acid can even oxidize copper as the nitrogen in the nitrate reduces from N+5 to N+4.

To balance the electrons in the reaction there must be twice as many nitrate reductions as copper oxidation reactions.

Cu(s) + 4 H+(aq) + 2 NO3-(aq) → Cu2+(aq) + 2 NO2(g) + 2 H2O(l)

Nitrogen dioxide is quite poisonous. Nitric acid spills on metals will produce this deadly gas. Nitric acid must be stored separately from other acids because of its special reactivity.